N,N,N′,N′-Tetra­kis(pyridin-4-yl)methane­diamine monohydrate

نویسندگان

  • Jong Won Shin
  • Kil Sik Min
چکیده

In the title compound, C(21)H(18)N(6)·H(2)O, two 4,4'-dipyridyl-amine groups are linked by a methyl-ene C atom, which sits on a twofold axis. The lattice water mol-ecule is located slightly off a twofold axis, and is therefore disordered over two positions. In the crystal, the organic mol-ecules and the water mol-ecule are linked by O-H⋯N hydrogen bonds. The organic mol-ecules exhibit extensive offset face-to-face π-π inter-actions to symmetry equivalents [centroid-centroid distances = 3.725 (3) and 4.059 (3) Å].

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Dichlorido[2-(pyridin-2-yl)-N-(pyridin-2-yl­methyl­idene)ethanamine-κ3 N,N′,N′′]manganese(II) monohydrate

In the title complex, [MnCl(2)(C(13)H(13)N(3))]·H(2)O, the Mn(II) atom is in a distorted square-pyramidal environment, with an Addison τ parameter of 0.037. The coordination geometry is defined by three N-atom donors from the tridentate 2-(pyridin-2-yl)-N-(pyridin-2-yl-methyl-idene)ethanamine ligand and two terminal Cl atoms. Although the H atoms of the lattice water molecule were not located, ...

متن کامل

N,N′-Dimethyl-N,N′-bis­(pyridin-2-yl)methane­diamine

The title compound, C(13)H(16)N(4), consists of two pyridine rings which are linked by an N,N'-dimethyl-methane-amine chain. The pyridine rings adopt a twist conformation and the dihedral angle between them is 60.85 (5)°. The crystal packing is stabilized by weak C-H⋯π inter-actions.

متن کامل

Tetra­aqua­bis­(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)­cobalt(II) monohydrate

In the title compound, [Co(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(4)]·H(2)O, the two 2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan-yl}acetate ligands are monodentate. One coordinates the metal atom via the pyridyl N atom whereas the other coordinates via the carboxyl-ate O atom. The Co(II) atom adopts a slightly distorted octa-hedral coordination geometry with four O atoms of the coordinated water mol...

متن کامل

Synthesis, Characterization and Study of Some N-Substituted Aryl-2- ({4-[(Substituted Aryl Carbamoyl) Methyl]-5-(Pyridin-4-yl)-4H-1, 2, 4-Triazol-3-yl} Sulfanyl) Acetamide

Pathogenic infections and inflammation are very common ailments humans suffer. Upsurge of resistant pathogens has impeded the antimicrobial drug development process in recent years and the search of new antimicrobial agents is clearly evident from the literature. In line with these developments the synthesis of N-substituted aryl-2-({4-[(substituted aryl carbamoyl) methyl]-5-(pyridin-4-yl)-4H-1...

متن کامل

4-[4,5-Bis(pyridin-2-yl)-1H-imidazol-2-yl]phenol monohydrate

In the title hydrate, C(19)H(14)N(4)O·H(2)O, the dihedral angle between the two pyridine rings is 38.0 (2)°. The dihedral angle between the imidazole and benzene rings is 25.3 (2)°. The crystal structure is stabilized by inter-molecular O-H⋯O, O-H⋯N and N-H⋯O hydrogen bonds.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012